
Department of Chemistry
University of South Florida
4202 E. Fowler Avenue, CHE 205A
Tampa, FL 33620-5250
Office: (813) 974-4487, CHE 205
Email: rmusselm@cas.usf.edu
B.S., California State University, Fresno, 1964
M.S., University of California, Davis, 1968
Ph.D, New Mexico State University, 1971
We use polarized specular reflectance UV/vis/IR spectroscopy and semi-empirical MO calculations and electronic state-transition modelling to study solid-state materials such as crystalline porphyrins, one-dimensional conductors and photovoltaic cell components. Specular reflectance means "mirror-like reflectance" and thus any very shiny, crystalline material with minimum dimension of at least 0.03 mm is a candidate for our instrument. The polarization aspect allows us to determine some specifics about electronic transitions, making transition assignments more reliable. In addition, our semi-empirical ZINDO calculations allow modelling of the transitions and orbitals to assign transitions with even more certainty. We also study solid-state effects of molecules, to study orbital perturbations and electron transfer in solids.
FRANKLIN AND MARSHALL COLLEGE, Lancaster, Pennsylvania
PRINCIPIA COLLEGE, Elsah, Illinois
STANFORD UNIVERSITY, Palo Alto, California
ARGONNE NATIONAL LABORATORY, Argonne, Illinois
LOUISIANA STATE UNIVERSITY, Baton Rouge